The Electrochemical Synthesis of Neutral Zinc(II) Complexes of Schiff Base Ligands: The Crystal Structure of Bis[N-(4-methylphenyl)salicylaldiminato]zinc(II)

نویسندگان

  • T. Sogo
  • J. Romero
  • A. Sousa
  • A. de Blas
  • M. L. Durán
  • E. E. Castellano
چکیده

X-Ray, Zinc, Schiff Bases, Electrochemical Synthesis The electrochemical synthesis and physico-chemical properties of neutral zinc(II) complexes of bidentate Schiff bases derived from salicylaldehydes are presented together with the X-ray structure of bis[N-(4-methylphenyl)salicylaldiminato]zinc(II). The crystal is monoclinic, a = 21.877(3), b = 8.801(2), c = 12.027(5) Ä , ß = 96.55(3)°, space group C2/c. The complex is a monomer, and the zinc atom is tetrahedrally coordinated.

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تاریخ انتشار 2012